Copper(I) Complexes with Thioether‐Functionalized Silylamido Ligands
نویسندگان
چکیده
The thioether-functionalized aminosilanes Me2Si(NH-C6H4-2-SR)2 (R=Ph, Me) were lithiated with n-BuLi and subsequently allowed to react CuCl in the presence of PMe3. In case Me2Si(NH-C6H4-2-SPh)2, dinuclear complex [Cu2{Me2Si(NC6H4-2-SPh)2}(PMe3)2] was isolated. copper atoms adopt a distorted trigonal-planar coordination (Cu−N: 191.2(2) pm, Cu−P: 216.3(1) Cu−S: 244.4(1) pm). reaction Li2Me2Si(N-C6H4-2-SMe)2 PMe3 led rearrangement processes from which ionic cluster compound [Cu(PMe3)4][Cu5{Me2Si(N-C6H4-2-S)(N-C6H4-2-S−Me)}2(PMe3)2] isolated low yield.
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2022
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202100339